Temporal evolution of granitic magmas in the Luanchuan metallogenic belt, east Qinling Orogen, central China: Implications for Mo metallogenesis

The Luanchuan metallogenic belt, located within the eastern part of the Qinling Orogen, central China, hosts a number of world-class Mo deposits that are closely related to small late Mesozoic granitic plutons. Zircon U-Pb dating of distinct plutons in the Luanchuan metallogenic belt has yielded ages of 153 +/- 1, 154 +/- 2, 152 +/- 2, and 148 +/- 1 Ma. Molybdenite Re-Os isotopic compositions of Yuku ore district in the southern part of Luanchuan metallogenic belt has yielded an isochron age of 146 +/- 1 Ma, which is consistent with the large-scale mineralization ages in the northern part of the Luanchuan metallogenic belt. A combination of previous studies and new geochronological and isotopic data show a concordant temporal and genetic link between granitic magmatism and Mo mineralization in the Luanchuan metallogenic belt, suggesting that this mineralization episode formed the most extensive Mo mineralization belt in the east Qinling Orogen. Zircon grains from Mo-related granitic plutons show similar trace element distributions. High-precision Multi Collector-Inductively Coupled Plasma-Mass Spectrometry (MC-ICP-MS) Pb isotope analysis of K-feldspar megacrysts from mineralization-related granites suggest that they were derived from the lower crust. Similarly, the Pb isotopic compositions of pyrite coprecipitated with molybdenite also suggest that the metals were derived form the lower crust, with probably minor mantle contribution. A continuum mineralization model that describes the sourcing of Mo from an evolving granitic magma over successive differentiation events, possibly in separate but connected magma chambers, could explain the remarkable Mo enrichment in the Luanchuan metallogenic belt. The volatile- and Mo-bearing granitic magmas ascended as diapirs from the deep crust, and were emplaced as dikes in the upper crust. Lithological differences between these Mo-bearing granites may relate to different stages in the evolution of individual magmas. Finally, ore-forming fluids were exsolved from the granitic melts in shallow-crustal magma chambers, resulting in the formation of the Mo deposits of the Luanchuan metallogenic belt. This model may account for the widespread late Mesozoic Mo deposits of eastern China. (c) 2015 Published by Elsevier Ltd.