期刊
PURE AND APPLIED CHEMISTRY
卷 73, 期 12, 页码 1917-1927出版社
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200173121917
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The electrochemical reduction of CO2 which includes a number of different specific approaches, may show promise as a means to help slow down the accumulation of this greenhouse gas in the atmosphere, Two types of approaches are examined briefly here. First, CO2 can be used as a reagent in the electrocarboxylation reaction to produce organic carboxylic acids, for example. the pharmaceutical ibuprofen. Second, CO2 can be converted to a fuel, either directly or via synthesis gas. The latter can be produced with reasonably good energy efficiency in a gas-diffusion, electrode-based cell even at present with existing electrocatalysts. Oxygen gas is produced as a by-product. Further work is needed to improve the selectivity and efficiency in this and other approaches.
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