期刊
HETEROCYCLES
卷 55, 期 12, 页码 2315-2324出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-01-9341
关键词
solvent effect; nonbenzenoid aromatic compound; charge distribution; ion pair; excited state
A solvent effect was found on the photoreactions of 1-aryl-3-tosyldihydro-1,3-diazaazulanones with a low pressure mercury lamp. Thus, ion pairs between p-toluenesulfonate anion and the corresponding 1-aryl-1,3-diazadihydroazulanone cations were afforded by the reactions in THF. On the other hand, the corresponding 1-aryl-1,3-diazaazulanones were formed by the reactions in the other solvents. The analogous photoreactions with 1-aryl-6-tosyldihydro-1,3-diazaazulanones afforded the corresponding 1-aryl-1,3-diazaazulanones.
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