期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 637, 期 -, 页码 823-826出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(01)00956-1
关键词
electrochemistry; biferrocene; bis(fulvalene)diiron; perfluorophenyl borate; supporting electrolyte; cyclic voltammetry
Cyclic voltammetry in CH2Cl2 containing 0.1 M [NBu4][B(C6F5)(4)] gives enhanced behavior for the oxidation of complexes containing two or more ferrocenyl groups, owing to better stabilities and solubilities of the multiply-charged oxidation products. The lower ion-pairing interaction of the anion [B(C6F5)(4)](-) with oligoferrocenyl multiply-charged cations leads to larger separations of the oxidation waves which may be exploited in studies of mixed-valent systems. (C) 2001 Elsevier Science B.V. All rights reserved.
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