期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 123, 期 48, 页码 11982-11990出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0114310
关键词
-
The reaction of bis(hexafluoroacetylacetonato)manganese(II) trihydrate (2), an similar to 90 degrees corner unit, with flexible linking unit 4,4'-trimethylenedipyridine (1) allows for the potential formation of three different types of solid-state coordination species: infinite helical polymers, closed dimeric systems, and infinite one-dimensional polymers. While the un-templated starting material is known to give a coordination helix, the other two possible species can be realized through the selective use of a variety of simple, organic guests: toluene (3), diphenylmethane (4), cis-stilbene (5), 1,3-diphenylpropane (6), benzyl alcohol (7), nitrobenzene (8), and cyanobenzene (9). When solutions of I and 2 are crystallized in the presence of all of these clathrates, the dimeric macrocycles result in all cases, except for that of 6, in which a syndiotactic, wedge-shaped polymer forms. Employing a linker that is less rigid than is typically used in crystal engineering, such as 1, enables the nucleophilic donor subunit to be more than just a simple spacer, instead making it an essential, tunable component in the overall crystal lattice. In so doing, a great deal of molecular information is lost, but this is compensated for by an in-depth investigation into the weaker host-guest and/or guest-guest interactions, such as nonclassical hydrogen bonding and an assortment of hydrophobic interactions, present in the various systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据