期刊
SCIENCE
卷 294, 期 5551, 页码 2527-2529出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1066595
关键词
-
We applied the velocity map imaging technique under high-resolution conditions to study ion pair products of the vacuum ultraviolet photodissociation of methyl chloride. We obtained rotationally resolved kinetic energy release spectra that directly provide vibrational frequencies and rotational constants of the fundamental carbocation, CH3+. The technique is analogous to photoelectron spectroscopy, with the chloride anion playing the rote of a heavy electron. The approach shows promise as a general probe of ionic species not amenable to study by traditional methods.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据