期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 35, 期 2, 页码 125-136出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0926-3373(01)00247-8
关键词
FT-IR; Ag-ZSM-5; hydrocarbon trap; toluene; propylene; cold-start
A detailed study of adsorption of automobile exhaust hydrocarbons in Ag+-exchanged zeolites under cold-start conditions (room temperature and in the presence of water) was carried out with FT-IR spectroscopy, using toluene and propylene as probes. The results show that exchanged Ag+ in zeolites is unique for trapping olefin and aromatic hydrocarbons due to its resistance to water adsorption. In contrast, exchanged Cu2+1 in zeolites, which has good hydrocarbon trapping properties under dry conditions, does not trap hydrocarbons under wet conditions. Here, solvation of Cu2+ screens the interactions of the cation with adsorbed hydrocarbons. The results also show that, in addition to the nature of the cation, the structure of the zeolite also plays a role in hydrocarbon trapping. Aging at high temperatures. with water vapor (similar to 10%) and SO2 (similar to 15 ppm), leads to a decrease of the trapping centers in the zeolites due to framework dealumination. (C) 2001 Elsevier Science B.V. All rights reserved.
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