期刊
CHEMICAL PHYSICS LETTERS
卷 350, 期 5-6, 页码 522-530出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(01)01316-1
关键词
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A new formulation of the configuration interaction (CI) method is presented. It is based on the recently introduced spin-flip (SF) approach. SF-Cl target states are described as spin-flipping excitations from the reference Hartree-Fock high-spin, e.g., M-s = 1 (\alphaalpha>), determinant. The resulting model is both variational and size-consistent. Moreover, the SF-CI model can describe within a single-reference formalism some inherently multi-reference situations, such as single bond-breaking and diradicals. Initial benchmarks for the SF-CI model with single and double substitutions (SF-CISD) are presented. (C) 2001 Published by Elsevier Science B.V.
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