The surface structure of the so-called Ag/Si(111)-(6 x 1) surface is studied by low-energy electron diffraction (LEED), high-resolution core-level photoelectron spectroscopy, and angle-resolved photoelectron spectroscopy. A c(12 x 2) phase is observed in LEED after cooling the room-temperature (6 x 1) phase to 100 K. In the Si 2p core-level spectra, no significant difference is observed between the two surfaces. In the valence-band spectra, five surface states are observed on both the (6 x 1) and c(12 x 2) surfaces. None of these surface states crosses the Fermi level. The binding energies and dispersions of the surface states observed on the (6 x 1) surface are quite similar to those of the c(12 x 2) surface. These results indicate that the basic structure of this Ag/Si(111) surface has a c(12 x 2) periodicity, and that the (6 x 1) Structure results from thermal vibrations of the surface atoms. Moreover, we assign two of the surface states to bonding states between Ag and Si atoms, and one of them to a pi-bond state.
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