期刊
TETRAHEDRON
卷 58, 期 4, 页码 653-659出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)01098-5
关键词
cytochrome P-450; enzyme mimics; steroids; remote oxidation; cyclodextrins
Five mimics of cytochrome P-450 have been prepared and examined as catalysts for the specific hydroxylation of steroids. Reactions occur dictated by the geometries of the complexes, overcoming the intrinsic reactivity of a carbon-carbon double bond and of a secondary carbinol group. In some cases as many as 3000 catalytic turnovers are observed. (C) 2002 Elsevier Science Ltd. All rights reserved.
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