期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 113, 期 1, 页码 97-100出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-1139(01)00496-1
关键词
oxalyl fluoride; cesium fluoride; 1,2-bis(2,2,2-trifluoroethoxy)-1,1,2,2-tetrafluoroethane; DFT calculation
The reactions of oxalyl fluoride with electrophiles in the presence of alkali metal fluoride were carried out. In the reaction with CF3CH2OTf (Tf = CF3SO2) or CH3CH2OTf, the synthesis of di-ether (ROCF2CF2OR) and mono-ether (ROCF2COF) was achieved. The difference of the reactivities between these two compounds was discussed from the result of DFT calculations. (C) 2002 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
