期刊
INORGANICA CHIMICA ACTA
卷 328, 期 -, 页码 39-44出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0020-1693(01)00659-4
关键词
Heck reaction; P-S hybrid ligands; palladium complexes; catalysis
The novel palladium phosphino-thioether P-S chelate complex, [PdCl2{MeSC6H4-2-(CH2PPh2)}] (3) is a highly efficient catalyst for the olefinic coupling of aryl bromo and iodo compounds to olefins under aerobic conditions, leading to more than 10(6) turnovers for the reactions with bromo and iodo benzenes. (C) 2002 Elsevier Science B.V. All rights reserved.
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