期刊
CHEMICAL PHYSICS LETTERS
卷 352, 期 5-6, 页码 348-352出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(01)01477-4
关键词
-
We examined the magnetic and thermal properties of a stable thiazyl radical 1,3,2-benzodithiazolyl, BDTA. While the diamagnetic room-temperature phase had been known for BDTA, we found a new phase transition to a paramagnetic solid phase at 346 K and a superheating process that resulted in the double melting (melt recrystallization-melt process) above 360 K. The supercooling of the paramagnetic high-temperature phase also occurred, leading to an antiferromagnetic ordering at 11 K with gamma-type anomaly in the temperature dependence of the heat capacity. Based on these data, the complex phase diagram of BDTA has been determined. (C) 2002 Published by Elsevier Science B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据