期刊
PHYSICAL REVIEW LETTERS
卷 88, 期 6, 页码 -出版社
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.88.063003
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Angular distributions of photoelectrons from a 2sigma g shell of fixed-in-space N-2 molecules have been measured for left- and right-elliptically polarized and for linearly polarized light at several photon energies in the region of sigma* shape resonance. That allowed the determination of a set of dipole matrix elements and phase shift differences characterizing the process. These data clearly show the enhancement of the f sigma(u) partial cross section in the resonance simultaneously with an abrupt increase of the corresponding phase shift by pi, which is the first experimental demonstration of the nature of the sigma* shape resonance in homonuclear diatomic molecules.
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