期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 67, 期 4, 页码 1118-1124出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0158433
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The oxidation of aniline in glacial acetic acid with percarbonate, a dry carrier of hydrogen peroxide, is a second-order reaction conforming to the isokinetic relationship. The hitherto followed method of correlation of the reaction rates in terms of the structure-reactivity relationships is unsatisfactory and erroneous. But the reaction rates of molecular anilines, obtained for the first time, conform to the structure-reactivity relationships.
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