期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 67, 期 4, 页码 1396-1398出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0108109
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An enantioselective total synthesis of hamacanthin B (1) is described. This synthesis is based on the asymmetric synthesis of (S)-2-azido-(indol-3-yl)ethylamine 7, which is coupled with the 3-indolyl-alpha-oxoacetyl chloride 8 and subsequently used in a successful intramolecular Staudinger-aza Wittig cyclization to form the central dihydropyrazinone ring. The stereochemistry of naturally isolated hamacanthin B is revealed as the (S)-configuration.
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