期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 124, 期 9, 页码 1977-1981出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0119200
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We report the first synthesis of a well-characterized Teflon ponytail fullerene adduct (3) via the Hirsch-Bingel reaction with a malonate bearing two pefluorinated alkyl chains, This C tris-adduct shows excellent solubility in perfluorinated solvents, such as FC-72 and FC-75. Compound 3 was found to be an efficient sensitizer for singlet oxygen formation in fluorous media, which has potential in biphasic systems and in photobiology.
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