期刊
ORGANIC LETTERS
卷 4, 期 5, 页码 715-717出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol017193v
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资金
- NIGMS NIH HHS [GM59384, GM60003] Funding Source: Medline
[GRAPHICS] The first total synthesis of (+/-)-jamtine (4), a tetrahydroisoquinoline alkaloid reputed for its therapeutic properties, is described. The key step involves a tandem thionium/N-acyliminium ion cyclization from enamido sulfoxide 13. The cascade process takes place with high diastereoselectivity and in excellent yield.
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