4.2 Article

Diversity-Oriented Synthesis of Substituted Furo[2,3-b]pyrazines

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AUSTRALIAN JOURNAL OF CHEMISTRY
卷 62, 期 1, 页码 27-41

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CSIRO PUBLISHING
DOI: 10.1071/CH08376

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  1. (Fund for Scientific Research - Flanders (Belgium))
  2. Katholieke Universiteit Leuven

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A highly efficient method for the synthesis of diversely substituted furo[2,3-b] pyrazines has been elaborated. The Ag+- or iodine-mediated electrophilic cyclization of readily generated 5-chloro-3-substituted ethynyl-1-(4-methoxybenzyl)pyrazin-2(1H)-ones affords substituted furo[2,3-b] pyrazines, which undergo various palladium catalyzed reactions to generate a library of difficult to attain diversely substituted furo[2,3-b] pyrazines.

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