期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 61, 期 6, 页码 419-421出版社
CSIRO PUBLISHING
DOI: 10.1071/CH08109
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A bismuth trifluoromethanesulfonate (triflate)-catalyzed (2.0 mol-%) multicomponent reaction involving the allylation of dioxolanes followed by in situ derivatization with anhydrides to generate highly functionalized esters has been developed under solvent-free conditions. Most reagents used to date for allylation of dioxolanes are highly corrosive and are often required in stoichiometric amounts. In contrast, the use of a relatively non-toxic and non-corrosive bismuth(III)-based catalyst makes this methodology especially attractive for scale-up.
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