期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 106, 期 10, 页码 2423-2425出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp0133687
关键词
-
The thermal spin transition between a high-spin state (S = 5/2) and an intermediate-spin state (S = 3/2) of the octhahedrally coordinated Mn(II)(3d(5)) was observed in Rb(I)Mn(II)[Fe(III)(CN)(6)] with a very wide hysteresis loop over the temperature range of 231 to 304 K. This phenomenon is accompanied by a structural distortion from the face-centered cubic structure to the tetragonal one caused by a cooperative Jahn-Teller effect in the octahedral Fe(III)C-6 moiety. To our knowledge, the present spin transition is the first observation in compounds containing a six-coordinated Mn(II).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据