期刊
ORGANIC LETTERS
卷 4, 期 6, 页码 957-960出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0255155
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资金
- NIAID NIH HHS [AI47818] Funding Source: Medline
[GRAPHICS] A mutational analysis of the enterocin biosynthesis genes revealed that the putative oxygenase and the methyltransferase gene products EncM and EncK, respectively, jointly catalyze a biosynthetic Favorskii-like rearrangement. Inactivation of either gene terminated enterocin production and caused the accumulation of four nonrearranged, nonmethylated polyketides. The structure elucidation of the new wailupemycins E-G is reported.
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