期刊
APPLIED CATALYSIS A-GENERAL
卷 228, 期 1-2, 页码 95-101出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0926-860X(01)00970-X
关键词
stannic; molybdenum; catalysts; oxidation; methanol; FT-IR spectroscopy
The mechanism of the selective oxidation of methanol on Sn-Mo oxide catalyst with molar ratio Mo/(Mo + Sn) = 0.3 is investigated. The interaction of methanol and its oxidation products (i.e. formaldehyde and methyl formate) is studied by FT-IR spectroscopy. The data are interpreted on the basis of a reaction mechanism which contains 10 elementary steps. The behaviors of the surface species (methoxy, formate and dioxymethylene groups) are compared with those monitored on other systems and the catalyst requirements for the title reaction are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据