期刊
SCIENCE
卷 295, 期 5564, 页码 2407-2409出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1067794
关键词
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Self-assembty of polymeric supramolecules is a powerful too[ for producing functional materials that combine several properties and may respond to external conditions. We illustrate the concept using a comb-shaped architecture. Examples include the hexagonal self-organization of conjugated conducting polymers and the polarized luminance in solid-state films of rodlike polymers obtained by removing the hydrogen-bonded side chains from the aligned thermotropic smectic phase. Hierarchically structured materials obtained by applying different self-organization and recognition principles and directed assembly form a basis for tunable nanoporous materials, smart membranes, preparation of nano-objects, and anisotropic properties, such as proton conductivity.
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