期刊
COMPTES RENDUS CHIMIE
卷 5, 期 4, 页码 309-318出版社
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/S1631-0748(02)01382-6
关键词
ferrocene; X-ray structure; dendrimers; phosphorus
New phosphorus-containing dendrimers bearing ferrocenyl units within the branches were synthesised using a new 1,1'-disubstituted ferrocenyl building block. The structure of one of the synthetic intermediates was determined by X-ray analysis. In every case, one single oxidation was observed for each ferrocenic layer. corresponding to the independent oxidation of all ferrocenes within one layer to ferroceniums. The oxidation potential for a particular layer depends on substituents on ferrocenes, but not on their localisation within the dendrimers. (C) 2002 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.
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