期刊
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
卷 99, 期 8, 页码 4932-4936出版社
NATL ACAD SCIENCES
DOI: 10.1073/pnas.012540799
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资金
- NIGMS NIH HHS [5R01GM57052, R01 GM057052] Funding Source: Medline
A family of nanoscale-sized supramolecular cage compounds with a trigonal prismatic framework was prepared by means of spontaneous self-assembly from the combination of a predesigned molecular clip with tritopic pyridyl subunits. As confirmed by x-ray crystallography, the smallest structure of the reported series is approximate to1 x 2 nm and possesses a nitrate anion incarcerated inside its molecular cavity. The largest structure has dimensions of approximate to 1 x 4 nm.
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