期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 649, 期 2, 页码 141-146出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)01110-5
关键词
N-heterocyclic silylenes; Pd complexes; mu-silylene complexes; X-ray structures
The reaction of N-heterocyclic silylenes (NHS) 1 and 2 with Pd complexes, notably [(tert-butyl)(3)P](2)Pd(0) and (COD)Pd(CH3)(2), is described. The formation of homoleptic NHS complexes Pd[Si((BuNCH2CH2NBu)-Bu-t-Bu-t)](4) and Pd[Si((BuNCHCHNBu)-Bu-t)](3) is reported. The rearrangement of these complexes into dinuclear silylene-bridged compounds and the solid state structures of the latter complexes are discussed. (C) 2002 Published by Elsevier Science B.V.
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