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TETRAHEDRON LETTERS
卷 43, 期 18, 页码 3359-3363出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00556-7
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A novel application of Pd-0-catalyzed arylation to mono N-arylated piperazines, its mechanism, and its application towards the novel syntheses of the key differentially N,N'-diarylated piperazine antifungal intermediate N-(4-hydroxyphenyl)-N'-(4-aminophenyl)piperazine 5 as well as posaconazole 1 are described. (C) 2002 Elsevier Science Ltd. All rights reserved.
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