4.6 Article

Ground-state energies for helium, H-, and Ps- -: art. no. 054501

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PHYSICAL REVIEW A
卷 65, 期 5, 页码 -

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AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.65.054501

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A triple basis set in Hylleraas coordinates is used to obtain improved variational bounds for the nonrelativistic energy and other properties of He, H-, and Ps(-). The accuracy, numerical stability, and computational efficiency are compared with recent work based on quasirandom basis sets. The Kato cusp conditions are used to assess the accuracy of the wave functions at short distances.

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