期刊
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
卷 177, 期 5, 页码 1137-1145出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500211718
关键词
H-1 and P-31 NMR; hydroxymethylphosphonates; mass spectrometry
This article describes the synthesis of a series of dialkylhydroxymethylphosphonates bearing various alkyl ester groups by the Pudovik reaction. The employed method uses anhydrous potassium carbonate as a catalyst in heterogeneous (solid/liquid) or mixed (solid/liquid and homogenous) conditions. All these syntheses are performed without any phase transfer agent and involve an anionic intermediate in a low polar or apolar solvent. These different products, obtained with high yields, have been characterised by H-1 and (PNMR)-P-31 and also by mass spectrometry. A study of fragmentation in the FAB ionisation process is given.
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