期刊
EUROPEAN POLYMER JOURNAL
卷 38, 期 5, 页码 977-981出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0014-3057(01)00249-X
关键词
microcapsule; polyamide; poly(acrylic acid) gel; copper extraction; size effect
In a previous work [J. Microencapsulation, in press], polyamide microcapsules containing a poly(acrylic acid) gel as a macromolecular ligand (PAA-CAPS) with a mean diameter of 210 mum were prepared using an original two-step polymerization process combining interfacial polycondensation and radical polymerization in a water in oil inverse emulsion system. Extractions of many divalent cations were examined. In this work, we proposed to synthesise by the same process, smaller microcapsules with a mean diameter of 10 mum (PAA-LCAPS). Reference polyamide microcapsules, i.e. without ligand were also synthesized (muCAPS) and (CAPS) [J. Microencapsulation, in press]. Microcapsule wall thickness was evaluated by SEM and TEM observations of microcapsule cross-section cuts, microcapsule water content was determined by thermogravimetric experiments. Specific surface area and total volume of the pore of microcapsules were determined by BET method based on N-2 adsorption/desorption. The comparison of the extractabilities and the stripping of Cu(II) into the various kind of microcapsules were examined. (C) 2002 Elsevier Science Ltd. All rights reserved.
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