期刊
JOURNAL OF APPLIED POLYMER SCIENCE
卷 132, 期 19, 页码 -出版社
WILEY
DOI: 10.1002/app.41956
关键词
films; networks; polycarbonates; ring-opening polymerization
资金
- JSR Co., Ltd.
The synthesis of six-membered cyclic carbonates from diols utilizing less toxic and easily-handled diphenyl carbonate (DPC) is carried out based on the reactivity and selectivity at different conditions. Commercially-available neopentylglycol (NPG) or di(trimethylolproapane) (DTMP) react effectively with DPC at 140 degrees C and converted to their corresponding monofunctional NPG-carbonate (NPGC) or bifunctional DTMPC-carboante (DTMPC), respectively. The selectivity of these carbonates changes depending on a feed ratio of DPC and these diols. After a NPG/DPC mixture with the DPC/NPG feed ratio of 4 was heated at 140 degrees C for 48 h, the NPGC is isolated with a yield of 74%. A 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed ring-opening polymerization (ROP) of NPGC with DTMPC can form effectively networked structures. By only drying of THF solutions containing NPGC, DTMPC, and a catalytic amount of DBU at 60 degrees C for 12 h, the ROP efficiently proceeds and networked polycarbonate films with well transparency and flexibility are easily obtained. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41956.
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