Persistence analysis of extreme CO, NO2 and O3 concentrations in ambient air of Delhi

Persistence analysis of air pollutant concentration and corresponding exceedance time series is carried out to examine for temporal evolution. For this purpose, air pollutant concentrations, namely, CO, NO2 and O-3 observed during 2000-2009 at a traffic site in Delhi are analyzed using detrended fluctuation analysis. Two types of extreme values are analyzed; exceeded concentrations to a threshold provided by national pollution controlling agency and time interval between two exceedances. The time series of three pollutants is observed to possess persistence property whereas the extreme value time series of only primary pollutant concentrations is found to be persistent. Two time scaling regions are observed to be significant in extreme time series of CO and NO2, mainly attributed to implementation of CNG in vehicles. The presence of persistence in three pollutant concentration time series is linked to the property of self-organized criticality. The observed persistence in the time interval between two exceeded levels is a matter of concern as persistent high concentrations can trigger health problems. (C) 2012 Elsevier B.V. All rights reserved.