期刊
ORGANIC LETTERS
卷 4, 期 9, 页码 1631-1634出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol025877c
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资金
- NIGMS NIH HHS [GM 35712] Funding Source: Medline
The effect of replacing the Bronsted acid in classic Passerini reactions with a mild Lewis acid has been studied. Triggered by metal-promoted silylation, condensations of aliphatic or aromatic carbonyl compounds with appropriately substituted isonitriles capable of neighboring group donation afford alpha-hydroxyamides, substituted oxazoles, and other useful heterocycles.
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