期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 67, 期 9, 页码 2798-2804出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo015910t
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A general strategy toward the synthesis of aryliodonium triflate salts has been exploited to afford derivatives that incorporate thiophene and bithiophene components. Both mono- and bis(iodonium) salts have been realized, and a series of bithienyl(aryl)iodonium triflates with increasingly electron-withdrawing substituents on the aryl moiety have been synthesized. X-ray crystallographic analysis of four derivatives (4a, 4b, 6b, and 8c) demonstrates that the solid-state organization of these salts incorporates extensive networks of secondary bonding interactions between the cationic iodonium centers and the triflate counterions. UV-vis spectroscopic analysis shows that the electronic interactions between pendent aryl and heteroaryl groups across the iodonium center can be dictated by substitution. Furthermore, the energy of the HOMO-LUMO gap decreases substantially in weakly or noncoordinating solvents.
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