期刊
TETRAHEDRON
卷 58, 期 20, 页码 3943-3949出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)00216-8
关键词
cobalt and compounds; diols; epoxides; fluorine and compounds
Cobalt complexes of fluorous chiral salen ligands have been synthesized and tested as catalysts in the hydrolytic kinetic resolution of terminal epoxides. Whereas the activity of heavily fluorinated complexes was found to be rather low, a 'light fluorous' complex was shown to be an efficient and highly selective catalyst for this asymmetric ring-opening reaction. Several strategies for the isolation of reaction products and the recovery of the fluorous catalyst are also discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.
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