期刊
PHYSICAL REVIEW B
卷 65, 期 20, 页码 -出版社
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevB.65.205106
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The electronic structure of CoO is studied by resonant inelastic soft x-ray scattering spectroscopy using photon energies across the Co 2p absorption edges. The different energy-loss structures in the Raman scattering spectra are identified as due to d-d and charge-transfer excitations. For excitation energies close to the L-3 resonance, the spectral features are dominated by quartet-quartet and quartet-doublet transitions of the 3d(7) configuration. At excitation energies corresponding to the satellites in the Co 2p x-ray-absorption spectrum of CoO, the emission features are instead dominated by charge-transfer transitions to the 3d(8)(L) under bar (-1) final state. The spectra are interpreted and discussed with the support of simulations within the single-impurity Anderson model with full multiplet effects which are found to yield consistent spectral functions to the experimental data.
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