4.5 Article

Entropy and temperature of a quantum Carnot engine

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ROYAL SOC
DOI: 10.1098/rspa.2001.0928

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quantum-mechanical engine; von Neumann entropy; thermodynamic equations of state

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It is possible to extract work from a quantum-mechanical system whose dynamics is governed by a time-dependent cyclic Hamiltonian. An energy bath is required to operate such a quantum engine in place of the heat bath used to run a conventional classical thermodynamic heat engine. The effect of the energy bath is to maintain the expectation value of the system Hamiltonian during an isoenergetic process. It is shown that the existence of such a bath leads to equilibrium quantum states that maximize the von Neumann entropy. Quantum analogues of certain thermodynamic relations are obtained that allow one to define the temperature of the energy bath.

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