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TETRAHEDRON LETTERS
卷 43, 期 26, 页码 4699-4702出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00817-1
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An efficient and mild Ru-catalyzed racemization of amines under transfer hydrogenation conditions is reported. A significant advantage of this new procedure is that the ruthenium hydrogen transfer catalysts allow high functional group tolerance. Interestingly, both primary and secondary amines were efficiently racemized under these conditions. We also report on the combination of this new amine racemization with an enzymatic kinetic resolution of primary amines. C 2002 Published by Elsevier Science Ltd.
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