4.4 Article

Solubility of glucose in mixtures containing 2-methyl-2-butanol, dimethyl sulfoxide, acids, esters, and water

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JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷 47, 期 4, 页码 807-810

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AMER CHEMICAL SOC
DOI: 10.1021/je0102457

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Solubility measurements of glucose in a variety of binary, ternary, and multicomponent mixtures containing 2-methyl-2-butanol, dimethyl sulfoxide, acids, esters, and water at different temperatures are presented. The solubilities of crystalline beta-glucose, amorphous beta-glucose, and amorphous beta-glucose in 2-methyl-2-butanol at 60 degreesC have also been measured. The results show that the solubilities of the amorphous forms in 2-methyl-2-butanol are higher than that of the corresponding crystalline form. The presence of dimethyl sulfoxide significantly increases glucose solubility in 2-methyl-2-butanol. Finally, the presence of glucose ester increases glucose solubility in 2-methyl-2-butanol, while the presence of fatty acid has the opposite effect.

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