期刊
TETRAHEDRON-ASYMMETRY
卷 13, 期 13, 页码 1449-1456出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0957-4166(02)00375-0
关键词
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Chiral perfluoroalkyl- and tris(perfluoroalkyl)silyl-derivatized analogues of the ligand MOP, having a fluorine content of 55.65 and 56.88%, respectively, have been prepared starting from optically active 6,6'-dibromo-2,2'-diethoxy-1,1'-binaphthyl. These ligands have been used in the palladium-catalyzed asymmetric substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate affording chiral products with e.e. of up to 37%. (C) 2002 Elsevier Science Ltd. All rights reserved.
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