期刊
JOURNAL OF CHROMATOGRAPHY A
卷 963, 期 1-2, 页码 249-257出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0021-9673(02)00543-5
关键词
water analysis; headspace analysis; volatile sulfur compounds; alkyl sulfides; sulfides; organosulfur compounds
An analytical procedure based on headspace solid-phase microextraction (SPME) followed by gas chromatography coupled to mass spectrometry in the electron impact mode has been developed for the determination of low-molecular-mass sulfides and disulfides in wastewater. Parameters affecting to the extraction of these volatile alkyl sulfides (VASs) with the SPME, such as the extraction temperature, sample volume, pH and the NaCl addition to the matrix, have been optimised using a polydimethylsiloxane-Carboxen fibre. The linear dynamic range was close to three orders of magnitude for all the studied compounds. Detection limits of 4 ng l(-1) for dimethyl sulfide, 0.7 ng l(-1) for ethylmethyl sulfide, 5 ng l(-1) for diethyl sulfide and 1 ng l(-1) for dimethyl disulfide were achieved, with a relative standard deviation between 4 and 6%. The developed analytical methodology was applied to determine those VASs in different wastewaters. (C) 2002 Elsevier Science B.V. All rights reserved.
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