期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 655, 期 1-2, 页码 134-145出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)01469-9
关键词
rhodium; copper; enantioselective hydrogenation; cyclopropanation; zeolites
The fixation of the preformed rhodium and copper complexes, [Rh(N,N'-bis[(S)-prolyl-N-(2-aminoethyl-3-aminopropyl)triethoxysilyl]ethylenediamine)(THF)]X, [Rh((N,N'-bis[(S)-benzyl prolyl]-N-(2-aminoethyl-3-aminopropyl)triethoxysilylethylenediamine)(cod)]X, X = PF6}, {[Cu(N,N'-bis[(S)-prolyl-N-(2-aminoethyl-3-aminopropyl)triethoxysilyl]ethylenediamine)]X, [Cu((N,N'-bis[(S)-benzylprolyl]-N-(2-aminoethyl-3-aminopropyl)triethoxysilylethylenediamine)(CH,CN)]X, X = ClO4 on zeolites (USY, MCM41) and their use, under heterogeneous conditions, for the hydrogenation and cyclopropanation reactions are reported. The catalytic activity and selectivity are higher to that observed tinder homogeneous conditions, as a consequence of the complex and/or reagents-to-support interaction. The strength of such interactions allows the recovery and recycling of the supported catalysts for a number of cycles. Atomic absorption analysis of the reaction solutions shows that there is no rhodium or copper leaching into the solutions. (C) 2002 Published by Elsevier Science B.V.
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