期刊
CHEMICAL ENGINEERING SCIENCE
卷 57, 期 16, 页码 3453-3460出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0009-2509(02)00215-4
关键词
filamentous active carbon; catalyst reuse; Pd dispersion; multiphase reactor; intrinsic kinetics; 2-butyne-1,4-diol hydrogenation; 2-butene-1,4-diol
Structured palladium catalysts suitable for three-phase reactions have been developed based on woven fabrics of active carbon fibres (ACF) as the catalytic supports. The Pd/ACF were tested in liquid-phase hydrogenation of 2-butyne-1,4-diol showing a selectivity towards 2-butene-1,4-diol up to 97% at conversions up to 80%. The catalyst multiple reuse with stable activity/selectivity in a batch reactor was also demonstrated. The reaction kinetics was studied and the main kinetic parameters were obtained. Assuming a Langmuir-Hinshelwood kinetics and a weak hydrogen adsorption a suitable kinetic model was developed consistent with the experimental data. (C) 2002 Elsevier Science Ltd. All rights reserved.
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