期刊
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
卷 43, 期 3-4, 页码 175-178出版社
SPRINGER
DOI: 10.1023/A:1021292111325
关键词
BF2+- capped complex; heavy metal extraction; octahedral cobalt(III) complex; synthetic macrocyclic ionophore
A new (E, E)-dioxime cobalt(III) complex [Co(HL)(2)pyCl] containing four 23-membered macrocyclic ionophores has been prepared. The cobalt(III) complex [Co(LBF2)(2)pyCl] bridged with BF2+ was prepared using the precursor cobalt(III) complex and boron trifluoride ethyl ether complex. The solvent extraction of heavy metal cations such as Ni2+, Cu2+, Zn2+, Hg2+ and Pb2+ by the BF2+-capped cobalt(III) complex has been investigated. The structure of the complexes is proposed according to elemental analyses, H-1 and C-13-NMR, IR and mass spectral data.
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