期刊
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
卷 40, 期 15, 页码 1682-1689出版社
JOHN WILEY & SONS INC
DOI: 10.1002/polb.10223
关键词
crystallization; dynamic mechanical analysis (DMA); intercalation; nanocomposites; poly(vinylidene fluoride) (PVDF); polymorphism
The preparation and properties of poly(vinylidene fluoride) (PVDF)/clay nanocomposites are reported for the first time. PVDF/clay nanocomposites were prepared by melt intercalation with organophilic clay. The composites were characterized with X-ray diffraction, differential scanning calorimetry, and dynamic mechanical analysis. X-ray diffraction results indicated intercalation of the polymer into the interlayer spacing. PVDF in the nanocomposites crystallized in the a beta form. Differential scanning calorimetry nonisothermal curves showed an increase in the melting and crystallization temperatures along with a decrease in crystallinity, as evidenced by the melting and crystallization peaks. Isothermal crystallization studies showed an enhanced rate of crystallization with the addition of clay, as evidenced by a reduction in the crystallization time. Dynamic mechanical analysis indicated significant improvements in the storage modulus over a temperature range of -100 to 150degreesC. The tan delta peak signifying the glass-transition temperature of PVDF shifted to higher temperatures. (C) 2002 Wiley Periodicals, Inc.
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