Synthesis of NiO nanorods by a novel simple precursor thermal decomposition approach

Single-crystal cubic NiO nanorods with diameters of 30-80 nm and lengths of up to tens of micrometers were synthesized by using a simple precursor thermal decomposition in NaCl flux with NiCO3 as the precursor, which was prepared by one-step, solid-state reaction of NiCl2 (.) 6H(2)O and Na2CO3 at ambient temperature. The crystallinity, purity, morphology, and structure features of the as prepared NiO nanorods were investigated by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), high-resolution transmission electron microscopy (HRTEM), and Raman spectrum. (C) 2002 Elsevier Science B.V. All rights reserved.