期刊
BIOMATERIALS
卷 23, 期 18, 页码 3799-3806出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0142-9612(02)00094-7
关键词
dental polymers; extent of polymerization; polymerization shrinkage; NMR; FTIR; STRAFI-MRI
The effect of dilution of 2,2-bis (4-(2-hydroxy-3-methacryloxyprop-1-oxy) phenyl) propane (Bis-GMA) with 2,2-bis(4-(2-methacryloxyprop-1-oxy)phenyl) propane (CH(3)Bis-GMA) on extent of polymerization (E-p) was investigated by FTIR and NMR. The results correlate well with E-p values of the system and its flexibility probed by T-g (obtained by DSC). Spatially resolved photopolymerization kinetics and polymerization shrinkage (PS, i.e. volumetric polymerization contraction) was also studied by stray-field imaging (STRAFI-MRI). PS was obtained in the presence of oxygen from the atmosphere as the total volumetric contraction. All the results were compared with those obtained for the Bis-GMA/TEGDMA (triethylene glycol dimethacrylate) system. Use of Bis-GMA mixed with hydrophobic low viscosity CH(3)Bis-GMA comonomer, as a substitute for the commonly used TEGDMA, resulted in improving significantly properties such as PS, water sorption and E-p thereby reducing the unreacted double bond concentration. (C) 2002 Elsevier Science Ltd. All rights reserved.
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