4.7 Article

C-S bond cleavage by cobalt:: synthesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments

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INORGANIC CHEMISTRY COMMUNICATIONS
卷 5, 期 9, 页码 649-652

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ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(02)00522-1

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1,2-Di-(o-salicylaldiminophenylthio)ethane; oxidative cleavage of C-S bond; crystal structure of Co(III) complex; activation by Co(II) salts

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1,2-Di-(o-salicylaldiminophenylthio)ethane reacts with Co(II) salts to form a complex with oxidative cleavage of the C-S bond, to result in the formation of a Co(III) complex of the cleaved ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

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