期刊
JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 307, 期 -, 页码 719-724出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0022-3093(02)01552-1
关键词
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H-1 NMR experiments on filled rubbers allow the observation of two features: the introduction of supplementary topological constraints by the fillers, and a layer of immobilised segments at the particle surface. In order to assess the role of the filler-elastomer interaction on the local chain dynamics, silica filled elastomer model systems were prepared. The synthesis methods used allowed us to test vastly different interaction strengths. It is shown that in the case of a weak interaction, the influence of the fillers is small, whereas a strong anchoring at the interface leads to an increase in the density of the topological constraints. The latter is correlated to a layer of highly immobilised segments whose thickness decreases with temperature. This layer is seen as a glassy shell. (C) 2002 Elsevier Science B.V, All rights reserved.
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